That's either Hero or House of the Flying Daggers. Based on the color saturation, I'm going to go with Hero.

Hero. Forget which sub-chapter - Edit: D'oh! Ninja'd. The color scheme gives it away though - that movie was all about color in the narratives . . .

Atlictoatl has it: Hero.

Damn me always being too late!

Dang, once again, I knew something and missed my chance.

That really, really looks like Anthony Hopkins, but I'm pretty sure that's Renegade.

Appaloosa? ._.; I'm rubbish with Western movies...

I think Brak's right...it looks like Michael Madsen in the turdtacular film "Renegade". (Based on the otherwise wonderful "Blueberry" comics by Moebius, not the Lorenzo Lamas series.) Google image search for "Renegade" and "Madsen" seems to confirm.

Agreed, it is Renegade.